1. Whisk together the balsamic vinegar, chicken broth, sugar, garlic, and Italian seasoning. Add chicken and marinate for 10 minutes on each side.
2. Heat the olive oil in a large skillet over medium-high heat. Remove the chicken from the marinade and reserve. Place chicken in the heated pan and cook until they start to brown and are no longer pink inside, about 7 minutes per side. Pour the marinade into the skillet and cook until it thickens slightly, turning the chicken breasts over once or twice, about 5 minutes.
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